Dangerous substances
Flammable gases, liquids and solids; oxidisers; self-reactive substances; pyrophorics; combustible dusts; gases under pressure; and substances capable of corroding metal containment.
Learn the Dangerous Substances and Explosive Atmospheres Regulations, identify dangerous substances and release sources, classify hazardous areas, control ignition sources, produce zone labels, manage actions and generate a professional DSEAR assessment report. This application supports competent assessment; it does not replace specialist hazardous-area classification or engineering verification where these are required.
Flammable gases, liquids and solids; oxidisers; self-reactive substances; pyrophorics; combustible dusts; gases under pressure; and substances capable of corroding metal containment.
Storage, transfer, mixing, spraying, heating, charging, cleaning, maintenance, waste handling, battery charging, gas use and any activity that creates a foreseeable release.
Operators, maintenance staff, contractors, visitors and the public may be exposed to flash fire, explosion, projectiles, pressure effects, burns, smoke or structural damage.
The lowest temperature at which a liquid gives off sufficient vapour to ignite under specified test conditions. Operating temperature, heating, spraying and mist formation can materially change risk.
The lower and upper explosive limits define the concentration range in air within which a gas or vapour mixture can propagate flame. Ventilation and detection should be designed around credible releases.
The temperature at which a substance can ignite without an external flame or spark. Equipment surface-temperature limits must provide an appropriate margin.
The energy needed to ignite a mixture. Very low-energy substances may be vulnerable to static discharge, switching sparks or mechanical impact.
Combustible dust risk depends on particle size, moisture, concentration, cloud formation, confinement and ignition sensitivity. Layers can create secondary explosions.
Continuous, primary and secondary releases, combined with ventilation effectiveness and availability, influence zone classification and extent.
Small components are manually wiped with isopropyl alcohol from a lidded dispenser. Waste wipes are placed in a self-closing metal bin. Ten litres are stored in a fire-resisting cabinet.
Potential releases: open dispensing, spill, saturated wipes and decanting.
Ignition sources: ordinary electrical equipment, static, hot work, portable devices and heated surfaces.
Reduce quantities, use closed dispensing, provide effective ventilation, bond and earth transfer containers where necessary, segregate ignition sources, control hot work, use suitable waste containers, inspect equipment and assess whether any zone exists around the release point.
Gas, vapour or mist explosive atmosphere present continuously, for long periods or frequently.
Highest gas/vapour occurrenceGas, vapour or mist explosive atmosphere likely to occur occasionally in normal operation.
Occasional normal-operation occurrenceGas, vapour or mist explosive atmosphere not likely in normal operation and, if it occurs, persists only briefly.
Abnormal and short durationCombustible dust cloud present continuously, for long periods or frequently.
Highest dust occurrenceCombustible dust cloud likely to occur occasionally in normal operation.
Occasional normal-operation occurrenceCombustible dust cloud not likely in normal operation and, if it occurs, persists only briefly.
Abnormal and short durationRemove the dangerous substance, hazardous operation or ignition source where reasonably practicable.
Use a less hazardous material or form, lower concentration, smaller inventory, lower temperature or closed delivery system.
Use closed systems, robust containment, compatible materials, high-integrity connections, controlled charging and preventive maintenance.
Provide ventilation, inerting, extraction, detection, interlocks and prompt removal of dust deposits or spills.
Select suitable electrical and mechanical equipment, control static, hot work, smoking, vehicles, mobile devices, friction, impact and hot surfaces.
Explosion relief or suppression, segregation, fire resistance, emergency shutdown, safe venting, alarms, evacuation and firefighting arrangements.
| Source | Typical examples | Expected control evidence |
|---|---|---|
| Electrical | Switchgear, motors, lighting, chargers, portable devices | Zone-compatible equipment selection, certification, inspection and maintenance. |
| Static electricity | Liquid transfer, powders, plastic containers, clothing | Bonding, earthing, conductive systems, controlled flow and verification. |
| Hot surfaces | Heaters, bearings, exhausts, lamps, process equipment | Temperature-class assessment, monitoring, maintenance and separation. |
| Flames and hot work | Welding, cutting, brazing, smoking | Permit-to-work, gas testing, isolation, fire watch and area release. |
| Mechanical sparks | Grinding, impact, seized bearings, dropped tools | Tool selection, condition monitoring, housekeeping and material compatibility. |
| Lightning and electromagnetic sources | Outdoor tanks, radio-frequency and induced currents | Engineering assessment, lightning protection and controlled equipment use. |
| Self-heating / chemical reaction | Oily rags, incompatible chemicals, reactive powders | Compatibility review, temperature control, waste management and segregation. |
Requires suitable and sufficient risk assessment, elimination or reduction of risk, safe handling/storage/transport, emergency arrangements, information and training, and classification of hazardous areas where explosive atmospheres may occur.
Approved Code of Practice and practical guidance for applying DSEAR. Use alongside the regulations and relevant industry guidance.
Widely used for explosive atmospheres, including area classification, equipment selection/installation, inspection, maintenance and repair. Select the applicable current parts through competent engineering review.
Explosion prevention and protection concepts, hazard identification and ignition-source consideration for equipment and protective systems.
Equipment intended for use in potentially explosive atmospheres must meet applicable product-safety requirements and carry appropriate conformity marking and certification.
Fire safety, pressure systems, COSHH, environmental controls, dangerous goods, building requirements and COMAH may also apply depending on the activity and inventory.
| Substance / process | Form | Quantity | Flash point / explosibility | LEL / key data | Storage/use | SDS/reference |
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| Area ID | Zone | Substance | Release source | Extent / drawing | Ventilation basis | Equipment requirement | Approval/status |
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| Action | Hierarchy | Owner | Due | Priority | Status | Closure evidence |
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